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Synthesis of Cyclotriveratrylene-Sucrose-Based Capsules

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journal contribution
posted on 06.08.2019, 21:43 by Łukasz Szyszka, Piotr Cmoch, Aleksandra Butkiewicz, Mykhaylo A. Potopnyk, Sławomir Jarosz
Cyclotriveratrylene (CTV) is a C3-symmetrical macrocycle, which can be used as a chiral building block in the construction of supramolecular containers. Coupling of the CTV unit with a sucrose molecule gave enantiopure water-soluble (after deprotection) containers. The absolute configuration of the synthesized capsules was determined by NMR and ECD spectroscopies and DFT calculations.