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Synthesis of Chiral (Diaminocarbene)Pd(allyl)Cl Complexes

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journal contribution
posted on 2004-06-07, 00:00 authored by Sylvain Roland, Max Audouin, Pierre Mangeney
Palladium(II)-allyl complexes bearing one chiral diaminocarbene ligand have been synthesized from the corresponding silver(I) complexes. The activation of these precatalysts by nucleophiles allowed the in situ generation of Pd(0) species, which are active in the Mizoroki−Heck reaction.