Synthesis of Chiral (Diaminocarbene)Pd(allyl)Cl
Complexes

Roland, Sylvain; Audouin, Max; Mangeney, Pierre

doi:10.1021/om040013b.s001

om040013b_si_001.pdf (180.63 kB)

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Synthesis of Chiral (Diaminocarbene)Pd(allyl)Cl Complexes

journal contribution

posted on 2004-06-07, 00:00 authored by Sylvain Roland, Max Audouin, Pierre Mangeney

Palladium(II)-allyl complexes bearing one chiral diaminocarbene ligand have been synthesized from the corresponding silver(I) complexes. The activation of these precatalysts by nucleophiles allowed the in situ generation of Pd(0) species, which are active in the Mizoroki−Heck reaction.