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Synthesis of (Arylalkenyl)silanes by Palladium-Catalyzed Regiospecific and Stereoselective Allyl Transfer from Silyl-Substituted Homoallyl Alcohols to Aryl Halides

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journal contribution
posted on 24.10.2007, 00:00 by Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima
The reactions of silyl-substituted homoallyl alcohols with aryl halides under palladium catalysis result in regiospecific and stereoselective allyl transfer from the alcohols to aryl halides, offering modular synthesis of (E)-3-aryl-1-alkenyl-, (E)-1-aryl-2-alkenyl-, and optically active (E)-1-aryl-2-butenylsilanes.

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