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Synthesis and Study of the First N-Aryl Acyclic Diaminocarbene and Its Transition-Metal Complexes

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journal contribution
posted on 03.04.2020, 16:48 by Evelyn L. Rosen, Matthew D. Sanderson, Shanmuganathan Saravanakumar, Christopher W. Bielawski
The first acyclic diaminocarbene (ADC) featuring N-aryl groups, as well as two complexes containing this ligand, (ADC)RhCl(1,5-cis,cis-cyclooctadiene) and (ADC)RhCl(CO)2, were synthesized and characterized. Insight into controlling conformational diversity in acyclic diaminocarbenes with N-aryl groups through judicious N substitution was also explored.