Synthesis and Structural Characterization of an
Exclusively N-Based Tetrameric Aluminum(I) Compound

Schiefer, Marcus; Reddy, N. Dastagiri; Roesky, Herbert W.; Vidovic, Denis

doi:10.1021/om0302793.s001

om0302793_si_001.pdf (601.5 kB)

Synthesis and Structural Characterization of an Exclusively N-Based Tetrameric Aluminum(I) Compound

journal contribution

posted on 2003-08-06, 00:00 authored by Marcus Schiefer, N. Dastagiri Reddy, Herbert W. Roesky, Denis Vidovic

The synthesis and X-ray structure of the first exclusively N-based tetrameric complex [RAl]₄ (1; R = 2,6-iPr₂C₆H₃N(SiMe₃)) are reported. 1 was prepared by the reduction of [RAlI₂]₂ (2) with Na/K alloy.

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Keywords

Pr Na Exclusively Structural Characterization Tetrameric synthesis tetrameric RAlI 2 Synthesi

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