American Chemical Society
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Synthesis and Structural Characterization of an Exclusively N-Based Tetrameric Aluminum(I) Compound

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journal contribution
posted on 2003-08-06, 00:00 authored by Marcus Schiefer, N. Dastagiri Reddy, Herbert W. Roesky, Denis Vidovic
The synthesis and X-ray structure of the first exclusively N-based tetrameric complex [RAl]4 (1; R = 2,6-iPr2C6H3N(SiMe3)) are reported. 1 was prepared by the reduction of [RAlI2]2 (2) with Na/K alloy.