American Chemical Society
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Synthesis and Solvatochromic Fluorescence of Biaryl Pyrimidine Nucleosides

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journal contribution
posted on 2013-05-17, 00:00 authored by Guillaume Mata, Nathan W. Luedtke
Fluorescent pyrimidine analogs containing a fused biphenyl unit were prepared in high yields using stereoselective N-glycosylation and Suzuki–Miyaura cross-coupling reactions. The resulting “push–pull” fluorophores exhibit highly solvatochromic emissions from twisted intramolecular charge-transfer (TICT) states.