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Synthesis and Properties of Short-Lifetime Thermally Activated Delayed Fluorescence Materials

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posted on 2023-06-15, 20:29 authored by Liang Zhang, Dingding Yang, Quanxing Li, Zhi-Jun Li, Wen-Bo Zhu, Kejian Chang, Haiyan Song, Chuan-Feng Chen
Compounds MBZ-mPXZ, MBZ-2PXZ, MBZ-oPXZ, EBZ-PXZ, and TBZ-PXZ were conveniently synthesized, and they were found to exhibit TADF properties with lifetimes of 857, 575, 561, 768, and 600 ns, respectively. These short lifetimes of the compounds might be due to the combination of small singlet–triplet splitting energy (ΔEST) and benzoate group, which could be an efficient strategy for the further design of short-lifetime TADF materials.

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