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Synthesis and Molecular Structure of a Perfluoroalkyl Complex of Platinum Containing a PCP Pincer Ligand

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journal contribution
posted on 22.09.2001, 00:00 by Russell P. Hughes, Alex Williamson, Christopher D. Incarvito, Arnold L. Rheingold
Treatment of (TMEDA)Pt(C3F7)Me (TMEDA = tetramethylethylenediamine) with 1,3-bis[(diphenylphosphino)methyl]benzene (PCPH) in mesitylene under reflux affords the first known pincer complex of a group 10 metal with a fluoroalkyl ligand.