om990266i_si_002.pdf (233.24 kB)
Synthesis and Characterization of the Dodecahexaynediyldiiron Complex, Fp*−(C⋮C)6−Fp* [Fp*= Fe(η5-C5Me5)(CO)2], the Longest Structurally Characterized Polyynediyl Complex
journal contribution
posted on 1999-07-17, 00:00 authored by Aizoh Sakurai, Munetaka Akita, Yoshihiko Moro-okaCu-catalyzed oxidative coupling of the hexatriynyl complex Fp*−(C⋮C)3−H affords the dodecahexynediyl diiron complex Fp*−(C⋮C)6−Fp*. Its linear but
slightly twisted structure has been revealed by X-ray
crystallography.