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Synthesis and Characterization of Heterobimetallic Iridium–Aluminum and Rhodium–Aluminum Complexes

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journal contribution
posted on 22.01.2018, 19:50 by Timothy P. Brewster, Tan H. Nguyen, Zhongjing Li, William T. Eckenhoff, Nathan D. Schley, Nathan J. DeYonker
We demonstrate the synthesis and characterization of a new class of late-transition-metal–aluminum heterobimetallic complexes via a novel synthetic pathway. Complexes of this type are exceedingly rare. Joint experimental and theoretical data sheds light on the electronic effect of ligands containing aluminum moieties on late-transition-metal complexes.