American Chemical Society
ol102384k_si_005.pdf (15.19 MB)

Synthesis, Reactivity, and Electronic Properties of 6,6-Dicyanofulvenes

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journal contribution
posted on 2010-11-19, 00:00 authored by Trisha L. Andrew, Jason R. Cox, Timothy M. Swager
A series of 6,6-dicyanofulvene derivatives are synthesized starting from masked, dimeric, or monomeric cyclopentadienones. The reactivities of 6,6-dicyanofulvenes relative to their parent cyclopentadienones are discussed. 6,6-Dicyanofulvenes are capable of undergoing two consecutive, reversible, one-electron reductions and are presented as potential n-type small molecules.