posted on 2016-11-18, 00:00authored byHui Jing, Lin Lu, Yakai Feng, Jun-Feng Zheng, Liandong Deng, Er-Qiang Chen, Xiang-Kui Ren
A novel
tetraphenylethylene material with liquid crystalline (LC)
helical structure and aggregation-induced emission (AIE) property
was prepared by ionic self-assembly (ISA). The AIE activity, phase
behavior, self-assembly structure, and molecular packing behavior
of the complex were then elucidated via a combination of different
experimental techniques such as UV–vis absorption spectra,
photoluminescence spectra, differential scanning calorimetry, polarized
optical microscopy, one- and two-dimensional X-ray diffraction, and
Fourier transform infrared spectroscopy. The experimental results
reveal that the ISA complex possesses high-efficiency luminescent
property with quantum yield as high as 46% in solid state. Meanwhile,
the complex could self-assemble into different interesting structures
which are sensitive to peripheral chain motions. During heating, the
complex takes a low-ordered helical supramolecular structure at ambient
temperature and then forms another LC phase with high-ordered helical
molecular stacking. These ordered hierarchical structures, in combination
with the liquid crystallinity and excellent AIE property of the ISA
complex, make it a promising material for fabrication of luminescent
devices.