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Suzuki−Miyaura Cross-Coupling of Potassium Trifluoroboratohomoenolates

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journal contribution
posted on 01.05.2008, 00:00 by Gary A. Molander, Daniel E. Petrillo
Ketone-, ester-, and amide-containing potassium trifluoroboratohomoenolates were prepared in good to excellent yields from the corresponding unsaturated carbonyl compounds. They were shown to be effective coupling partners in the Suzuki-Miyaura reaction with a variety of electrophiles including electron-rich and electron-poor aryl bromides and -chlorides.