posted on 2024-02-06, 06:04authored byHao Li, Jia Bin Niu, Kay Jin Tay, Mei Chee Tan, Hong Yee Low
Micropores significantly impact the adsorption properties
of porous
materials, but their effective utilization often encounters diffusion
limitations. Introducing hierarchical pore structures offers a promising
solution. However, the sustainable fabrication of hierarchical structures
remains challenging. Additionally, previous fabrication methods typically
involve the use of nitrogen-containing compounds, complicating the
exploration of the relationship between pore structure and CO2 capture properties due to CO2’s strong
affinity for N-containing groups. Here, we report a dual-template
approach to sustainably fabricate hierarchically porous carbon (HPC)
and systematically investigate the effect of pore hierarchy on CO2 capture. The resulting interconnected multiscale porous adsorbent
exhibits superior CO2 capture properties than that of other
nitrogen-free porous adsorbents. The pore structure with high hierarchy,
encompassing extra-large, macro-, meso-, and microscale features,
shows a 27% enhancement in CO2 capture capacity compared
to that without extra-large and mesopores. Moreover, this HPC retains
its uptake capacity and kinetics after 20 adsorption–desorption
cycles, showcasing robust stability. This study provides a sustainable
strategy for optimizing micropore sites, offering valuable insights
for the design of advanced porous materials tailored for adsorption-related
applications.