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Surfactant 1‑Hexadecyl-3-methylimidazolium Chloride Can Convert One-Dimensional Viologen Bromoplumbate into Zero-Dimensional

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journal contribution
posted on 24.04.2017, 15:06 by Guangfeng Liu, Jie Liu, Lina Nie, Rui Ban, Gerasimos S. Armatas, Xutang Tao, Qichun Zhang
A zero-dimensional N,N′-dibutyl-4,4′-dipyridinium bromoplumbate, [BV]6[Pb9Br30], with unusual discrete [Pb9Br30]12– anionic clusters was prepared via a facile surfactant-mediated solvothermal process. This bromoplumbate exhibits a narrower optical band gap relative to the congeneric one-dimensional viologen bromoplumbates.

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