Supramolecular Tiling of a Conformationally Flexible Precursor

Supramolecular self-assembly offers a possible pathway for nanopatterning and functionality. In particular, molecular tiling such as trihexagonal tiling (also known as the Kagome lattice) has promising chemical and physical properties. Distorted Kagome lattices are not well understood due to their complexity, and studies of their controllable fabrication are few. Here, by employing a conformationally flexible precursor, 2,4,6-tris­(3-bromophenyl)-1,3,5-triazine (mTBPT), we demonstrate two-dimensional distorted Kagome lattice p3, (333) by supramolecular self-assembly and achieve tuning of the metastable phases, including the homochiral porous network and distorted Kagome lattice p3, (333) by steering deposition rates on a cold Ag(111) substrate. By a combination of scanning tunneling microscopy and density functional theory calculations, the distorted Kagome lattice is energetically unfavorable but can be trapped at a high deposition rate, and the process mainly depends on surface kinetics. This work using conformationally flexible mTBPT molecules provides a pathway for the controllable growth of different phases, including metastable Kagome lattices.