Superb Alkali-Resistant Dy^III₂Ni^II₄ Single-Molecule Magnet

A superb alkali-resistant single-molecule-magnet (SMM) material with the molecular formula [Dy₂Ni₄(L)₈(CH₃COO)₄(NO₃)₂] (1) (HL = 8-hydroxyquinoline) has been structurally and magnetically characterized. Single-crystal X-ray diffraction revealed that 1 possesses a hexanuclear [Dy^III₂Ni^II₄] cluster, which is built by two triangular [Dy^IIINi^II₂] cores double-bridged through two CH₃COO^– ions. Interestingly, 1 can keep its original structure in dilute acid and common basic solutions (e.g., triethylamine and NaOH). More importantly, 1 is still stable after treatment with a 20 M NaOH aqueous solution for 1 month at room temperature. Magnetic measurements uncovered that 1 is an SMM under zero applied field with U_eff = 7.43 K. To the best of our knowledge, 1 is the first example of a 3d–4f SMM with such extreme alkali resistance. This work will broaden the vision of preparing SMM materials with excellent chemical stability.