A dehydrative
cross-coupling of unactivated allylic alcohols with
sulfinic acids was achieved under catalyst-free conditions. This reaction
proceeded via allyl sulfination and concomitant allyl sulfinate–sulfone
rearrangement. Various allylic sulfones could be obtained in good
to excellent yields with water as the only byproduct. This study expands
the synthetic toolbox for constructing allylic sulfone molecules.