ol052957i_si_001.pdf (552.91 kB)
Download file

Substitution of Hydroxyl Groups with Alkynyl Moieties Using Alkynylboron Dihalides:  An Efficient Approach to Secondary Alkylacetylene Derivatives

Download (552.91 kB)
journal contribution
posted on 02.03.2006, 00:00 authored by George W. Kabalka, Min-Liang Yao, Scott Borella
The reaction of alkynylboron dihalides with benzylic, allylic, and propargylic alcohols provides an efficient route to internal acetylenes. Isomerization of the product alkynes does not occur under the reaction conditions.