ol0501469_si_001.pdf (1.13 MB)

Substitution and Remote Protecting Group Influence on the Oxidation/Addition of α-Substituted 1,2-Anhydroglycosides:  A Novel Entry into C-Ketosides

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journal contribution
posted on 17.03.2005, 00:00 by Scott W. Roberts, Jon D. Rainier
C-Ketosides are valuable intermediates in chemical synthesis and as glycoside mimics. This manuscript describes the efficient generation of these substrates from α-alkyl-substituted glycals and an oxidative, C−C bond-forming sequence where the choice of C(3) protecting group was critical.