Substituent-Enabled Oxidative
Dehydrogenative Cross-Coupling
of 1,4-Naphthoquinones with Alkenes

Zhang, Chi; Wang, Meining; Fan, Zhoulong; Sun, Li-Ping; Zhang, Ao

doi:10.1021/jo501419s.s001

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Substituent-Enabled Oxidative Dehydrogenative Cross-Coupling of 1,4-Naphthoquinones with Alkenes

journal contribution

posted on 15.08.2014, 00:00 authored by Chi Zhang, Meining Wang, Zhoulong Fan, Li-Ping Sun, Ao Zhang

A Rh-catalyzed oxidative dehydrogenative cross-coupling of 1,4-naphthquinones with alkenes was achieved by using a substituent-enabled C(sp²)–H functionalization (SEF) strategy. The method shows high functional group tolerance, broad substrate scope, and great potential for further functional transformations.

Substituent-Enabled Oxidative Dehydrogenative Cross-Coupling of 1,4-Naphthoquinones with Alkenes

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