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Sterically Crowded Gallium Amidinate Complexes

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journal contribution
posted on 07.10.1999, 00:00 by Samuel Dagorne, Richard F. Jordan, Victor G. Young
The sterically crowded gallium amidinate complexes {tBuC(NR‘)2}GaX2 (X = Cl, Me, Et, CH2Ph; R‘ = iPr, Cy, tBu) have been synthesized in good yield. X-ray crystallographic analyses show that the steric interactions between the tBu and R‘ groups influence the R‘−N−Ga angle and the steric environment at gallium.