ol0269594_si_001.pdf (9.65 MB)

Stereospecific Synthesis of Highly Substituted Skipped Dienes through Multifunctional Palladium Catalysis

Download (9.65 MB)
journal contribution
posted on 05.11.2002, 00:00 by Avinash N. Thadani, Viresh H. Rawal
Multifunctional palladium catalysis is utilized in the one-pot stereocontrolled synthesis of tetrasubstituted alkenes. The homogeneous palladium dihalide catalyst utilized for bromo-/chloroallylation of alkynes is then reused in situ for a subsequent Suzuki cross-coupling reaction.