ol200834p_si_001.pdf (1.01 MB)

Stereoselective Synthesis of a Model C(18)–C(35) Spiroketal Fragment of Integramycin

Download (1.01 MB)
journal contribution
posted on 20.05.2011, 00:00 by Huikai Sun, Jason R. Abbott, William R. Roush
A highly stereoselective synthesis of a model C(18)–C(35) spiroketal unit (7) of integramycin has been accomplished via an enantioselective stannyl-crotylboration reaction and an N-iodosuccinimide-mediated spiroketalization of 19a.

History