American Chemical Society
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Stereoselective Synthesis of Dienes from N-Allylhydrazones

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journal contribution
posted on 2009-01-15, 00:00 authored by Devon A. Mundal, Kelly E. Lutz, Regan J. Thomson
A new method for the stereoselective synthesis of dienes from aldehydes and N-allylhydrazine derivatives has been developed. High levels of (E)-stereoselectivity are obtained for a variety of substrates. Addition of a dienophile to the reaction mixture allows a one-flask diene synthesis−cycloaddition sequence.