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Stereocontrolled Reactions Mediated by a Remote Sulfoxide Group:  Synthesis of Optically Pure anti-β-Amino Alcohols

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journal contribution
posted on 13.11.2003, 00:00 by José L. García Ruano, José Alemán
A one-step synthesis of enantiomerically pure anti-1,2-amino alcohol derivatives has been achieved by reaction of prochiral oxygenated 2-p-tolylsulfinylbenzyl carbanions with N-sulfinylimines bearing the same configuration at sulfur.