American Chemical Society
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Stable (Amino)(phosphino)carbenes:  Difunctional Molecules

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journal contribution
posted on 2002-05-22, 00:00 authored by Nathalie Merceron, Karinne Miqueu, Antoine Baceiredo, Guy Bertrand
(Amino)(phosphino)carbenes are stable due to the donation of the nitrogen lone pair, the phosphino group remains strongly pyramidalized. Reactions can be performed selectively at the carbene center, but also at the phosphorus center leading to new stable carbenes. These difunctional molecules can be considered as hybrid ligands.