ol101435w_si_001.pdf (2.56 MB)

Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones

Download (2.56 MB)
journal contribution
posted on 06.08.2010, 00:00 by Masanobu Nagano, Mitsunobu Doi, Masaaki Kurihara, Hiroshi Suemune, Masakazu Tanaka
Chiral cyclic α-amino acid containing oligopeptide catalyzed highly enantioselective epoxidation of α,β-unsaturated ketones and the α-helical secondary structure of the peptide catalyst were revealed by X-ray crystallographic analysis.

History