ja050856+_si_003.pdf (195.23 kB)
Download file

Sorption−Desorption Behavior of Bispyrazolato−Copper(II) 1D Coordination Polymers

Download (195.23 kB)
journal contribution
posted on 04.05.2005, 00:00 by Augusto Cingolani, Simona Galli, Norberto Masciocchi, Luciano Pandolfo, Claudio Pettinari, Angelo Sironi
A new polycrystalline vapochromic polymorph of the one-dimensional copper bispyrazolate polymer reversibly and selectively absorbs a number of small molecules; the crystal structures of the anhydrous and fully hydrated species, determined by powder diffraction methods, are markedly different despite their simple, fast, and reversible interconversion.