posted on 2021-11-24, 18:34authored byApurba Pramanik, Basil Raju Karimadom, Haya Kornweitz, Mindy Levine
Reported herein is
the synthesis, characterization, and dye removal
applications of a highly solvent-selective organogel-forming amide,
compound 1, which contains a 1,8-naphthalmide moiety,
flexible n-hexyl chain, and benzene ring. This compound
displayed remarkable solvent selectivity, with gel formation occurring
only in the presence of alkylated aromatic solvents. Detailed structural
characterization of the gels, combined with notable theoretical insights,
is invoked to explain the highly selective gelation properties of
compound 1, as is a comparison to non-gel forming structural
isomer 2, which contains the same structural elements
in a different arrangement. Finally, the ability of the gel derived
from compound 1 to act as a reusable material for the
efficient removal of cationic organic dyes from contaminated aqueous
environments is also reported, with up to 11 repeated uses of the
gel still maintaining the ability to effectively remove Rhodamine
B.