American Chemical Society
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Solvent-Free Synthesis of Crystalline Metal Phosphate Oxalates with a (4,6)-Connected fsh Topology

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journal contribution
posted on 2015-10-05, 00:00 authored by Lindong Luan, Jing Li, Cheng Chen, Zhien Lin, Hui Huang
Two new organically templated manganese phosphate oxalates were synthesized under solvent-free conditions. They have different three-dimensional structures with a (4,6)-connected fsh topology. It is interesting that the amine molecules can reverse the structure-building roles of the metal phosphate skeleton and metal oxalate substructure for formation of their fsh-type frameworks.