American Chemical Society
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Solvent-Free Microwave-Assisted Synthesis of 2,5-Dimethoxyphenylaminotriazines

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journal contribution
posted on 2015-12-07, 00:00 authored by José R. Ramírez, Rubén Caballero, Javier Guerra, Amparo Ruiz-Carretero, Ana Sánchez-Migallón, Antonio de la Hoz
The green synthesis of asymmetric star-shaped 2,5-dimethoxyphenylamino-1,3,5-triazine derivatives using microwave irradiation in the absence of solvent is described. The title compounds have been characterized, and their properties as donor–acceptor (D–A) systems have been studied by UV–vis, fluorescence spectroscopy and electrochemical studies. The formation of excimers and the aggregation of these star-shaped triazine systems have been demonstrated.