Organocalcium compounds (post-Grignard
reagents) of the type [Ca(R)(X)(L)n] are
very reactive and able to degrade ethers
with α- and β-deprotonation as possible first reaction
step. In this systematic study, the durability of phenyl-, α-naphthyl-,
and 1,2-dihydronaphth-4-ylcalcium derivatives in cyclic ethers such
as tetrahydrofuran (THF), tetrahydropyran (THP), and α-methyltetrahydrofuran
(Me-THF) is investigated. The temperature, solvent, and the nature
of the second anionic ligand X [iodide, bis(trimethylsilyl)amide,
α-naphthyl] significantly influence the durability of their
ethereal solutions.