posted on 2019-10-30, 19:45authored byShengkai Yang, Kelei Zhuo, Zezhong Zhang, Jianming Liu, Guangyue Bai, Jianji Wang
The
low yield of graphene in the sonication-assisted aqueous-phase
exfoliation is one of the challenges to its large-scale production
in industry. Here, we report that hydrothermal exfoliation of graphite
into graphene in NaF and polyether F127 (F127) solution can achieve
a high concentration (0.55 mg mL–1) or yield (8.2%)
of graphene in a low-cost, environmentally friendly manner. The defect
of as-exfoliated graphene is comparable to that produced by the sonication-assisted
exfoliation. In the exfoliation process, NaF and F127 are regarded
as the intercalator and stabilizer. The thermal motion of H2O and F–/Na+ ion pairs, Brownian motion
of graphite particles, and thermally agitation of graphite interlayers
are the main driving force for exfoliating graphite. In addition,
as filler of epoxy resin (EP), the graphene can enhance considerably
the anticorrosion performance of EP coating. The hydrothermal exfoliation
in NaF and F127 solution provides a new choice for the large-scale
production of graphene.