The lithiation/delithiation in LiFePO4 is highly anisotropic
with lithium-ion diffusion being mainly confined to channels along
the b-axis. Controlling the orientation of LiFePO4 crystals therefore plays an important role for efficient
mass transport within this material. We report here the preparation
of single crystalline LiFePO4 nanosheets with a large percentage
of highly oriented {010} facets, which provide the highest pore density
for lithium-ion insertion/extraction. The LiFePO4 nanosheets
show a high specific capacity at low charge/discharge rates and retain
significant capacities at high C-rates, which may benefit the development
of lithium batteries with both favorable energy and power density.