Two-dimensional
(2D) materials stand as a promising platform for
tunnel field-effect transistors (TFETs) in the pursuit of low-power
electronics for the Internet of Things era. This promise arises from
their dangling bond-free van der Waals heterointerface. Nevertheless,
the attainment of high device performance is markedly impeded by the
requirement of precise control over the 2D assembly with multiple
stacks of different layers. In this study, we addressed a thickness-modulated
n/p+-homojunction prepared from Nb-doped p+-MoS2 crystal, where the issue on interface traps can be neglected
without any external interface control due to the homojunction. Notably,
our observations reveal the existence of a negative differential resistance,
even at room temperature (RT). This signifies the successful realization
of TFET operation under type III band alignment conditions by a single
gate at RT, suggesting that the dominant current mechanism is band-to-band
tunneling due to the ideal interface.