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Simultaneous Polymerization and Schulz−Flory Oligomerization of Ethylene Made Possible by Activation with MAO of a C1-Symmetric [2,6-Bis(arylimino)pyridyl]iron Dichloride Precursor

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journal contribution
posted on 20.12.2004, 00:00 by Claudio Bianchini, Giuliano Giambastiani, Itzel Rios Guerrero, Andrea Meli, Elisa Passaglia, Tania Gragnoli
C1-symmetric [2,6-bis(imino)pyridyl]iron dichloride complexes can form on activation by MAO highly active catalysts for the one-pot transformation of ethylene into mixtures of linear homopolymer and α-olefins with a Schulz−Flory distribution.