American Chemical Society
ol061904d_si_002.pdf (200.2 kB)

Simultaneous Ejection of Six Electrons at a Constant Potential by Hexakis(4-ferrocenylphenyl)benzene

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journal contribution
posted on 2006-10-26, 00:00 authored by Vincent J. Chebny, Dwairath Dhar, Sergey V. Lindeman, Rajendra Rathore
A simple synthesis of a dendritic hexaferrocenyl electron donor (5) is described in which six ferrocene moieties are connected at the vertices of the propeller of the hexaphenylbenzene core. The molecular structure of 5 is confirmed by X-ray crystallography. An electrochemical analysis along with redox titrations (which are tantamount to coulometry) confirmed that it ejects six electrons at a single potential.