ol061904d_si_002.pdf (200.2 kB)
Simultaneous Ejection of Six Electrons at a Constant Potential by Hexakis(4-ferrocenylphenyl)benzene
journal contributionposted on 2006-10-26, 00:00 authored by Vincent J. Chebny, Dwairath Dhar, Sergey V. Lindeman, Rajendra Rathore
A simple synthesis of a dendritic hexaferrocenyl electron donor (5) is described in which six ferrocene moieties are connected at the vertices of the propeller of the hexaphenylbenzene core. The molecular structure of 5 is confirmed by X-ray crystallography. An electrochemical analysis along with redox titrations (which are tantamount to coulometry) confirmed that it ejects six electrons at a single potential.