Silver-Catalyzed Imination of Sulfoxides
and Sulfides

Cho, Gae Young; Bolm, Carsten

doi:10.1021/ol0519442.s001

ol0519442_si_001.pdf (9.32 MB)

Silver-Catalyzed Imination of Sulfoxides and Sulfides

journal contribution

posted on 2005-10-27, 00:00 authored by Gae Young Cho, Carsten Bolm

Silver salts in the presence of a chelating ligand efficiently catalyze the stereospecific imination of sulfoxides and sulfides with sulfonylamides and PhI(OAc)₂ to afford sulfoximines and sulfilimines, respectively, in good yields.

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Keywords

PhI chelating ligand presence sulfilimine catalyze sulfide sulfoximine Sulfoxide sulfoxide Imination stereospecific imination Sulfides Silver salts sulfonylamide yield

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