Silver-Catalyzed Formal Inverse Electron-Demand Diels–Alder Reaction of 1,2-Diazines and Siloxy Alkynes
journal contribution
posted on 2016-02-20, 20:12 authored by Yunus
E. Türkmen, Timothy
J. Montavon, Sergey A. Kozmin, Viresh H. RawalA highly effective silver-catalyzed formal inverse electron-demand
Diels–Alder reaction of 1,2-diazines and siloxy alkynes has
been developed. The reactions provide ready access to a wide range
of siloxy naphthalenes and anthracenes, which are formed in good to
high yields, under mild reaction conditions, using low catalyst loadings.
