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Silver-Catalyzed Formal Inverse Electron-Demand Diels–Alder Reaction of 1,2-Diazines and Siloxy Alkynes

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journal contribution
posted on 2016-02-20, 20:12 authored by Yunus E. Türkmen, Timothy J. Montavon, Sergey A. Kozmin, Viresh H. Rawal
A highly effective silver-catalyzed formal inverse electron-demand Diels–Alder reaction of 1,2-diazines and siloxy alkynes has been developed. The reactions provide ready access to a wide range of siloxy naphthalenes and anthracenes, which are formed in good to high yields, under mild reaction conditions, using low catalyst loadings.

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