Sequential Unsymmetrical Aryl Coupling
of <i>o</i>-Substituted Aryl Iodides with
<i>o</i>-Bromophenols and Reaction with
Olefins: Palladium-Catalyzed Synthesis
of 6<i>H</i>-Dibenzopyran Derivatives
posted on 2006-08-31, 00:00authored byElena Motti, Fiorenza Faccini, Ilaria Ferrari, Marta Catellani, Raffaella Ferraccioli
Dibenzopyran derivatives are prepared by palladium- and norbornene-catalyzed reaction of aryl iodides, <i>o</i>-substituted with electron-releasing
substituents, <i>o</i>-bromophenols, and activated alkenes.