ma060972c_si_001.pdf (227.92 kB)
Self-Diffusion of Linear Polymers within Microcapsules
journal contributionposted on 2006-10-31, 00:00 authored by Kristin E. Price, Steven J. Broadwater, Andrew R. Bogdan, Ivan Keresztes, Jeremy L. Steinbacher, D. Tyler McQuade
We present a new strategy for the heterogenization of catalysts. The strategy relies on the containment of soluble polymers within a polyurea microcapsule. Diffusion ordered spectroscopy and spin−spin relaxation measurements are used to demonstrate that the encapsulated polymer is behaving as if it is in solution, not as a solid. Since the interior polymer behaves as if it is in solution, it should be possible to modify the capsule and polymeric contents separately.