Selective and Environmentally Friendly
Methodologies Based on the Use of
Electrochemistry for Fine Chemical
Preparation:  An Efficient Synthesis of
N,N‘-Disubstituted Ureas

Chiarotto, Isabella; Feroci, Marta

doi:10.1021/jo034750d.s001

Selective and Environmentally Friendly Methodologies Based on the Use of Electrochemistry for Fine Chemical Preparation: An Efficient Synthesis of N,N‘-Disubstituted Ureas

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posted on 2003-08-15, 00:00 authored by Isabella Chiarotto, Marta Feroci

A novel efficient synthesis of N,N‘-disubstituted ureas has been developed. Aromatic and aliphatic primary amines undergo oxidative carbonylation under atmospheric pressure of carbon monoxide using Pd(II) catalyst in combination with its anodic recycling at a graphite electrode.

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oxidative carbonylation Aromatic Chemical aliphatic Pd Urea disubstituted ureas Efficient Synthesis Selective synthesis amines combination graphite electrode Electrochemistry Preparation anodic recycling carbon monoxide Environmentally Friendly Methodologies catalyst

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CC BY-NC 4.0

Selective and Environmentally Friendly Methodologies Based on the Use of Electrochemistry for Fine Chemical Preparation: An Efficient Synthesis of N,N‘-Disubstituted Ureas

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