ol6b02250_si_001.pdf (2.71 MB)
Selective Rhodium-Catalyzed C–H Amidation of Azobenzenes with Dioxazolones under Mild Conditions
journal contribution
posted on 2016-08-26, 13:48 authored by Bomi Jeon, Uiseong Yeon, Jeong-Yu Son, Phil Ho LeeA synthetic
method for a wide range of amidated azobenzenes is
developed from the selective rhodium-catalyzed C–H amidation
reaction of symmetrical as well as unsymmetrical azobenzenes with
alkyl-, aryl-, and heteroaryl-substituted dioxazolones under mild
conditions. Diamidation of azobenzenes and amidation of monoamidated
azobenzenes were also demonstrated.