American Chemical Society
ja6b01376_si_001.pdf (4.76 MB)

Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts

Download (4.76 MB)
journal contribution
posted on 2016-02-25, 00:00 authored by Adelphe M. Mfuh, John D. Doyle, Bhuwan Chhetri, Hadi D. Arman, Oleg V. Larionov
We report herein a simple, metal- and additive-free, photoinduced borylation of haloarenes, including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids. This borylation method has a broad scope and functional group tolerance. We show that it can be further extended to boronic esters and carried out on gram scale as well as under flow conditions.