posted on 1999-10-13, 00:00authored byYasuhiro Morisaki, Teruyuki Kondo, Take-aki Mitsudo
CpRuCl(cod)/NH4PF6 (Cp = cyclopentadienyl, cod = 1,5-cyclooctadiene) is an effective
catalyst system for the allylic substitution of cyclic allyl carbonates with nucleophiles. This
catalyst system enables the first investigation of the stereochemical course of the ruthenium-catalyzed allylic substitution reaction, in which the reaction proceeds with an overall
retention of configuration. The stoichiometric reaction of trans-5-(methoxycarbonyl)cyclohex-2-enyl chloride with Cp*RuCl(cod) (Cp* = pentamethylcyclopentadienyl) gave the unexpected
complex Cp*Ru(η6-C6H5CO2Me)+ by the rapid dehydrohalogenation/dehydrogenation of the
desired Cp*RuCl2(η3-C6H8CO2Me) complex.