RuCl3-Catalyzed Oxidation of Iodoarenes with
Peracetic Acid:  New Facile Preparation of
Iodylarenes

Koposov, Alexey Y.; Karimov, Rashad R.; Pronin, Andrey A.; Skrupskaya, Tatyana; Yusubov, Mekhman S.; Zhdankin, Viktor V.

doi:10.1021/jo062073s.s001

jo062073s_si_001.pdf (596.16 kB)

RuCl₃-Catalyzed Oxidation of Iodoarenes with Peracetic Acid: New Facile Preparation of Iodylarenes

journal contribution

posted on 2006-12-22, 00:00 authored by Alexey Y. Koposov, Rashad R. Karimov, Andrey A. Pronin, Tatyana Skrupskaya, Mekhman S. Yusubov, Viktor V. Zhdankin

New facile methodology for the preparation of pentavalent iodine compounds using peracetic acid as an oxidant in the presence of catalytic amounts of ruthenium trichloride is described. The new procedure allows the preparation of several previously unknown iodylarenes bearing strongly electron-withdrawing CF₃ groups in the aromatic ring.