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Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Aliphatic and Aromatic Terminal Alkynes with Aliphatic Primary Amines
journal contribution
posted on 2021-09-07, 21:31 authored by Yoshihiko Morimoto, Takuya Kochi, Fumitoshi KakiuchiAnti-Markovnikov hydroamination of
both aliphatic and aromatic
terminal alkynes with primary amines was achieved using an 8-quinolinolato
rhodium catalyst to form aldimines and enamines in high yields. This
catalytic system realized high functional group tolerance including
hydroxy, bromo, cyano, and thioester groups.