Rh2(II)-Catalyzed Synthesis of Carbazoles from Biaryl Azides

Stokes, Benjamin J.; Jovanović, Brankica; Dong, Huijun; Richert, Kathleen J.; Riell, Ryan D.; Driver, Tom G.

doi:10.1021/jo9002536.s003

Rh₂(II)-Catalyzed Synthesis of Carbazoles from Biaryl Azides

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posted on 2009-04-17, 00:00 authored by Benjamin J. Stokes, Brankica Jovanović, Huijun Dong, Kathleen J. Richert, Ryan D. Riell, Tom G. Driver

An array of carbazoles (23 examples) can be synthesized from substituted biaryl azides at 60 °C using substoichiometric quantities of Rh₂(O₂CC₃F₇)₄ or Rh₂(O₂CC₇H₁₅)₄.

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biaryl azides Rh substoichiometric quantities Biaryl Azides

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Rh₂(II)-Catalyzed Synthesis of Carbazoles from Biaryl Azides

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